This book is written after a course C183:Startup Thiel held in Stanford. That means it's not only a collection of bright ideas, advices and anecdotes - it's structured like a course, and it's a very good course. Thiel has his own angle on the Blue Ocean Strategy and it's pretty convincing. A must read.
Not quite a business book, but it unveils a lot of detail about the great SpaceX/Tesla story, which is unfolding before our eyes. Unlike some other stories, here the man behind it is one of the main factors of success, which makes it a prime role book for entrepreneurship.